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Citation:
 Mohamed Djermouni,Ahmed Ouadha.Evaluating Ammonia and Methanol as Lower-Emission Alternatives to liquefied natural gas for Medium-speed Marine Engines: A Thermodynamic Analysis[J].Journal of Marine Science and Application,2025,(4):729-743.[doi:10.1007/s11804-024-00600-5]
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Evaluating Ammonia and Methanol as Lower-Emission Alternatives to liquefied natural gas for Medium-speed Marine Engines: A Thermodynamic Analysis

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Title:
Evaluating Ammonia and Methanol as Lower-Emission Alternatives to liquefied natural gas for Medium-speed Marine Engines: A Thermodynamic Analysis
Author(s):
Mohamed Djermouni Ahmed Ouadha
Affilations:
Author(s):
Mohamed Djermouni Ahmed Ouadha
Laboratoire des Sciences et Ingénierie Maritimes, Faculté de Génie Mécanique, Université des Sciences et de la Technologie Mohamed Boudiaf d’Oran, Oran El-Mnouar, 31000 Oran, Algeria
Keywords:
AmmoniaMethanolLiquefied natural gasThermodynamicMedium-speedDual-fuelEngine
分类号:
-
DOI:
10.1007/s11804-024-00600-5
Abstract:
This work investigates the potential of low-pressure, medium-speed dual-fuel engines for cleaner maritime transportation. The thermodynamic performance of these engines is explored using three alternative fuels: liquefied natural gas (LNG), methanol, and ammonia. A parametric analysis examines the effect of adjustments to key engine parameters (compression ratio, boost pressure, and air–fuel ratio) on performance. Results show an initial improvement in performance with an increase in compression ratio, which reaches a peak and then declines. Similarly, increases in boost pressure and air–fuel ratio lead to linear performance gains. However, insufficient cooling reduces the amount of fuel burned, which hinders performance. Exergy analysis reveals significant exergy destruction within the engine, which ranges from 69.96% (methanol) to 78.48% (LNG). Notably, the combustion process is the leading cause of exergy loss. Among the fuels tested, methanol exhibits the lowest combustion-related exergy destruction (56.41%), followed by ammonia (62.12%) and LNG (73.77%). These findings suggest that methanol is a promising near-term alternative to LNG for marine fuel applications.

References:

[1] Agarwal AK, Kumar V, Ankur Kalwar AJ (2022) Fuel injection strategy optimisation and experimental performance and emissions evaluation of diesel displacement by port fuel injected methanol in a retrofitted mid-size genset engine prototype. Energy 248: 123593. https://doi.org/10.1016/j.energy.2022.123593
[2] Al-Aboosi FY, El-Halwagi MM, Moore M, Nielsen RB (2021) Renewable ammonia as an alternative fuel for the shipping industry. Curr. Opin. Chem. Eng. 31: 100670. https://doi.org/10.1016/jxoche.2021.100670
[3] Altosole M, Balsamo F, Campora U, Mocerino L (2021) Marine dual-fuel engines power smart management by hybrid turbocharging systems. J. Mar. Sci. Eng 9: 663-679. https://doi.org/10.3390/JMSE9060663
[4] Bejan A (2016) Advanced engineering thermodynamics. 3rd edn, John Wiley & Sons, Inc., Hoboken, USA
[5] Benvenuto G, Campora U, Laviola M, Terlizzi G, Benvenuto G, Campora U, Laviola M, Terlizzi G (2017) Simulation model of a dual-fuel four stroke engine for low emission ship propulsion applications. Int. Rev. Mech. Eng. 11: 817-824. https://doi.org/10.15866/IREME.V11I11.11929
[6] Cardoso JS, Silva V, Rocha RC, Hall MJ, Costa M, Eusébio D (2021) Ammonia as an energy vector: Current and future prospects for low-carbon fuel applications in internal combustion engines. J. Clean. Prod. 296: v126562. https://doi.org/10.1016/j.jclepro.2021.126562
[7] Carlucci AP, de Risi A, Laforgia D, Naccarato F (2008) Experimental investigation and combustion analysis of a direct injection dual-fuel diesel-natural gas engine. Energy 33: 256-263. https://doi.org/10.1016/j.energy.2007.06.005
[8] Cengel Y (2003) Heat transfer: A practical approach. 2nd edn, McGraw-Hill, New York
[9] Chen Z, He J, Chen H, Geng L, Zhang P (2021) Comparative study on the combustion and emissions of dual-fuel common rail engines fueled with diesel/methanol, diesel/ethanol, and diesel/n-butanol. Fuel 304: 121360. https://doi.org/10.1016/j.fuel.2021.121360
[10] Chmielniak T, Sciazko M (2003) Co-gasification of biomass and coal for methanol synthesis. Appl. Energy 74: 393-403
[11] Dimitriou P, Tsujimura T (2017) A review of hydrogen as a compression ignition engine fuel. Int. J. Hydrogen Energy 42: 24470-24486. https://doi.org/10.1016/j.ijhydene.2017.07.232
[12] European Environment Agency (2021) European Maritime Transport Environmental Report. Available from https://www.eea.europa.eu/publications/maritime-transport/ [Accessed on Sept. 11, 2022]
[13] Ferguson CR, Kirkpatick AT (2001) Internal combustion engines: Appied thermosciences. John Wiley & Sons, Inc., Hoboken, USA
[14] Frerichs J, Eilts P (2022) A new combustion model for medium speed dual-fuel engines in the course of 0D/1D simulation. Methane 1: 158-176. https://doi.org/10.3390/METHANE1030013
[15] Gong C, Wei F, Si X, Liu F (2018) Effects of injection timing of methanol and LPG proportion on cold start characteristics of SI methanol engine with LPG enriched port injection under cycle-by-cycle control. Energy 144: 54-60. https://doi.org/10.1016/J.ENERGY.2017.12.013
[16] Heywood JB (2018) Internal combustion engine fundamentals. 2nd edn, McGraw Hill, New York
[17] International Maritime Organization (2020) Fourth IMO greenhouse gas study: Executive summary. IMO. Available from https://www.cdn.imo.org/localresources/en/OurWork/Environment/Documents/Fourth%20IMO%20GHG%20Study%202020%20Executive-Summary.pdf [Accessed on Sept. 10, 2024]
[18] Jamrozik A, Tutak W, Pyrc M, Gruca M, Ko?i?ko M (2018) Study on co-combustion of diesel fuel with oxygenated alcohols in a compression ignition dual-fuel engine. Fuel 221: 329-345. https://doi.org/10.1016/J.FUEL.2018.02.098
[19] Karim GA (2015) Dual-fuel diesel engines. 1st edn, CRC Press, Boca Raton, USA. https://doi.org/10.1201/b18163
[20] Karl M, Jonson JE, Uppstu A, Aulinger A, Prank M, Sofiev M, Jalkanen JP, Johansson L, Quante M, Matthias V (2019) Effects of ship emissions on air quality in the Baltic Sea region simulated with three different chemistry transport models. Atmos. Chem. Phys. 19: 7019-7053. https://doi.org/10.5194/ACP-19-7019-2019
[21] Kotas TJ (1985) The exergy method of thermal plant analysis. Butterworths, London, UK. https://doi.org/10.1016/C2013-0-00894-8
[22] Krishnamoorthi M, Sreedhara S, Duvvuri PP (2021) The effect of low reactivity fuels on the dual fuel mode compression ignition engine with exergy and soot analyses. Fuel 290: 120031. https://doi.org/10.1016/j.fuel.2020.120031
[23] Kurien C, Mittal M (2022) Review on the production and utilization of green ammonia as an alternate fuel in dual-fuel compression ignition engines. Energy Convers. Manag. 251: 114990. https://doi.org/10.1016/j.enconman.2021.114990
[24] Latarche M (2021) Pounder’s marine diesel engines and gas turbines. 10th edn, Elsevier, Oxford, UK
[25] Li J, Wu B, Mao G (2015) Research on the performance and emission characteristics of the LNG-diesel marine engine. J. Nat. Gas Sci. Eng. 27: 945-954. https://doi.org/10.1016/J.JNGSE.2015.09.036
[26] Li L, Wei J, Liu H, Wang H, Yao M (2023) The exergy analysis of low carbon or carbon free fuels: Methane, methanol, and hydrogen under engine like conditions. Fuel Process Technol. 252: 107975. https://doi.org/10.1016/J.FUPROC.2023.107975
[27] Lide DR (1991) Handbook of radiation chemistry: Edited by Y. Tabata, Y. Ito and S. Tagawa. CRC Press, Boca Raton, Florida. 1991. Int. J. Radiat. Appl. Instrumentation. Part C. Radiat. Phys. Chem. 38: 503-504. https://doi.org/10.1016/1359-0197(91)90071-9
[28] Lienhard JHI, Lienhard JHV (2008) A heat transfer textbook. 3rd edn, Phlogiston Press, Cambridge (MA), USA
[29] Liu X, Srna A, Yip HL, Kook S, Chan QN, Hawkes ER (2021) Performance and emissions of hydrogen-diesel dual direct injection (H2DDI) in a single-cylinder compression-ignition engine. Int. J. Hydrogen Energy 46: 1302-1314. https://doi.org/10.1016/J.IJHYDENE.2020.10.006
[30] Ma B, Yao A, Yao C, Chen C, Qu G, Wang W, Ai Y (2021) Multiple combustion modes existing in the engine operating in diesel methanol dual fuel. Energy 234: 121285. https://doi.org/10.1016/j.energy.2021.121285
[31] Ma B, Yao A, Yao C, Wu T, Wang B, Gao J, Chen C (2020) Exergy loss analysis on diesel methanol dual fuel engine under different operating parameters. Appl. Energy 261: 114483. https://doi.org/10.1016/j.apenergy.2019.114483
[32] MAN B&W (2012) ME-GI dual fuel MAN B&W engines: A technical, operational and cost-effective solution for ships fuelled by gas. MAN Diesel & Turbo. Available form https://maritimeexpert.files.wordpress.com/2018/02/me-gi-dual-fuel-man-b-amp-w-engines.pdf [Accessed on Sept. 10, 2024]
[33] Mavrelos C, Theotokatos G (2018) Numerical investigation of a premixed combustion large marine two-stroke dual fuel engine for optimising engine settings via parametric runs. Energy Convers. Manag. 160: 48-59. https://doi.org/10.1016/j.enconman.2017.12.097
[34] Millington BW, Hartles ER (1968) Frictional losses in diesel engines. SAE Technical Paper, 680590. https://doi.org/10.4271/680590
[35] Moran MJ, Shapiro HN, Boettner DD, Bailey MB (2014) Fundamentals of engineering thermodynamics. 8th edn, John Wiley & Sons, Inc., Hoboken, USA
[36] Müller M, Pfeifer M, Holtz D, Müller K (2024) Comparison of green ammonia and green hydrogen pathways in terms of energy efficiency. Fuel 357: 129843. https://doi.org/10.1016/J.FUEL.2023.129843
[37] Nadimi E, Przyby?a G, Lewandowski MT, Adamczyk W (2023) Effects of ammonia on combustion, emissions, and performance of the ammonia/diesel dual-fuel compression ignition engine. J. Energy Inst. 107: 101158. https://doi.org/10.1016/j.joei.2022.101158
[38] Panda K, Ramesh A (2022) Parametric investigations to establish the potential of methanol based RCCI engine and comparison with the conventional dual fuel mode. Fuel 308: 122025. https://doi.org/10.1016/J.FUEL.2021.122025
[39] Reiter AJ, Kong SC (2011) Combustion and emissions characteristics of compression-ignition engine using dual ammonia-diesel fuel. Fuel 90: 87-97. https://doi.org/10.1016/j.fuel.2010.07.055
[40] Ritzke J, Andree S, Theile M, Henke B, Schleef K, Nocke J, Hassel E (2016) Simulation of a dual-fuel large marine engines using combined 0/1-D and 3-D approaches. Proceedings of the 28th CIMAC World Congress on Combustion Engine Technology, Helsinki, Finland, 6-10
[41] Selmane F, Djermouni M, Ouadha A (2021) Thermodynamic modeling of a turbocharged diesel-hydrogen dual-fuel marine engine. J. Inst. Eng. Ser. C 102: 221-234. https://doi.org/10.1007/s40032-020-00633-z
[42] Shen B, Su Y, Yu H, Zhang Y, Lang M, Yang H (2023) Experimental study on the effect of injection strategies on the combustion and emissions characteristic of gasoline/methanol dual-fuel turbocharged engine under high load. Energy 282: 128925. https://doi.org/10.1016/J.ENERGY.2023.128925
[43] Stoumpos S, Theotokatos G, Boulougouris E, Vassalos D, Lazakis I, Livanos G (2018) Marine dual fuel engine modelling and parametric investigation of engine settings effect on performance-emissions trade-offs. Ocean Eng. 157: 376-386. https://doi.org/10.1016/j.oceaneng.2018.03.059
[44] Stoumpos S, Theotokatos G, Mavrelos C, Boulougouris E (2020) Towards marine dual fuel engines digital twins—Integrated modelling of thermodynamic processes and control system functions. J. Mar. Sci. Eng. 8: 200. https://doi.org/10.3390/JMSE8030200
[45] Theotokatos G, Stoumpos S, Bolbot V, Boulougouris E (2020) Simulation-based investigation of a marine dual-fuel engine. J. Mar. Eng. Technol. 19: 5-16. https://doi.org/10.1080/20464177.2020.1717266
[46] Vancoillie J (2013) Modeling the combustion of light alcohols in spark-ignition engines. PhD thesis, Ghent University, Ghent, Belgium
[47] Wang B, Yao A, Yao C, Chen C, Wang H (2020) In-depth comparison between pure diesel and diesel methanol dual fuel combustion mode. Appl. Energy 278: 115664. https://doi.org/10.1016/j.apenergy.2020.115664
[48] Wang C, Liu H, Zhang M, Zhong X, Wang H, Jin C, Yao M (2023) Experimental and kinetic modeling studies on oxidation of methanol and di-tert-butyl peroxide in a jet-stirred reactor. Combust. Flame 258: 113093. https://doi.org/10.1016/J.COMBUSTFLAME.2023.113093
[49] Wang Q, Wei L, Pan W, Yao C (2015) Investigation of operating range in a methanol fumigated diesel engine. Fuel 140: 164-170. https://doi.org/10.1016/j.fuel.2014.09.067
[50] Wärtsilä (2019) Wärtsilä 50DF product guide. Wärtsilä Finland Oy. Available from https://cdn.wartsila.com/docs/default-source/product-files/engines/df-engine/product-guide-o-e-w50df.pdf [Accessed on Sept. 10, 2024]
[51] Wärtsilä (2016) Record book of engine parameters. Wärtsilä Finland Oy, Finland
[52] Watson N, Janota MS (1982) Turbocharging the internal combustion engine. Palgrave MacMillan Press LTD, London, UK. https://doi.org/10.1007/978-1-349-04024-7
[53] Yates A, Bell A, Swarts A (2010) Insights relating to the autoignition characteristics of alcohol fuels. Fuel 89: 83-93. https://doi.org/10.1016/j.fuel.2009.06.037
[54] Yu H, Chen J, Duan S, Sun P, Wang W, Tian H (2022). Effect of natural gas injection timing on performance and emission characteristics of marine low speed two-stroke natural gas/diesel dual-fuel engine at high load conditions. Fuel 314: 123127. https://doi.org/10.1016/j.fuel.2021.123127
[55] Zacharakis-Jutz G (2013) Performance characteristics of ammonia engines using direct injection strategies. Master thesis, Iowa State University, Ames, USA
[56] Zhen X, Wang Y, Xu S, Zhu Y (2013) Numerical analysis on knock for a high compression ratio spark-ignition methanol engine. Fuel 103: 892-898. https://doi.org/10.1016/j.fuel.2012.10.023

Memo

Memo:
Received date:2024-2-13;Accepted date:2024-8-10。<br>Corresponding author:Mohamed Djermouni,E-mail:djermounimohamed@yahoo.fr
Last Update: 2025-08-27