|Table of Contents|

Citation:
 G. Subramanian,S. Palraj and S. Palanichamy.Galvanic Corrosion Behaviour of Aluminium 3004 and Copper in Tropical Marine Atmosphere[J].Journal of Marine Science and Application,2014,(2):230-236.[doi:10.1007/s11804-014-1244-z]
Click and Copy

Galvanic Corrosion Behaviour of Aluminium 3004 and Copper in Tropical Marine Atmosphere

Info

Title:
Galvanic Corrosion Behaviour of Aluminium 3004 and Copper in Tropical Marine Atmosphere
Author(s):
G. Subramanian S. Palraj and S. Palanichamy
Affilations:
Author(s):
G. Subramanian S. Palraj and S. Palanichamy
1. Offshore Platform & Marine Electrochemistry Centre, CSIR-CECRI Unit, Harbour Area, Tuticorin-628004, India 2. CSIR-Central Electrochemical Research Institute, Karaikudi-630006, India
Keywords:
aluminium 3004 copper galvanic corrosion corrosion products pitting tropical marine atmosphere
分类号:
-
DOI:
10.1007/s11804-014-1244-z
Abstract:
The galvanic corrosion behaviour of aluminium 3004 and copper with different area ratios were studied in the tropical marine atmosphere at Tuticorin harbour over a period of 426 days. The area ratios of AAl : ACu, studied were 1:1, 1:2, 1:4, 1:8, 2:1, 4:1 & 8:1. The galvanic corrosion behaviour of metals was studied in terms of relative increase in the corrosion rate of aluminium due to galvanic coupling with copper, relative decrease in the corrosion rate of copper due to galvanic coupling with aluminium, and the susceptibility of aluminium to pitting owing to galvanic coupling with copper. The galvanic potential and galvanic current of the system were monitored. Pits of different dimensions ranging from mild etchings to perforations were experienced on the borders and the surfaces of the interface of aluminium in contact with copper. The weathering parameters and the environmental pollutants which have a major role in influencing the galvanic corrosion of metals were also monitored. The corrosion products resulting from galvanic corrosion were analysed using XRD and the pitting on aluminium resulting from galvanic corrosion has been highlighted in terms of pit depth, size and density of pit, using a high resolution microscope.

References:

ASTM standards (2003). Standard practice for preparing, cleaning, and evaluating corrosion test coupons. ASTM International, West Conshohocken, PA, United States, Designation G1-03.
ASTM standards (2005). Standard guide for examination and evaluation of pitting corrosion. ASTM International, West Conshohocken, PA, United States, Designation G46-94.
Campbell HS (1950). Pitting corrosion in copper water pipes caused by films of carbonaceous material produced during manufacture. Journal of the Institute of Metals, 77, 345-348.
Champion FA (1952). Corrosion testing procedures. Chapman & Hall, London, UK, 36-52.
Compton KG, Mendizza A (1955). Galvanic couple corrosion studies by means of the threaded bolt and wire test. ASTM 58th Annual Meeting, Symposium on Atmospheric Corrosion of Non-ferrous Metals, Philadelphia, USA, 116-125.
Dey AK, Sinha Mahapatra AK, Khan DK, Mukherjee AN, Narain R, Mukherjee KP, Banerjee T (1966). Interim report on atmospheric corrosion studies under marine atmosphere. NML Tech. J. India, 8(4), 11-16.
Doyle DP, Wright TE (1988). Quantitative assessment of atmospheric galvanic corrosion. ASTM STP 978 Galvanic Corrosion, Philadelphia, USA, 161-173.
Foster RL, Lucas KE, Hack HP, Bieberich B, Jackovic T (1996). Long-term current and potential data for selected galvanic couples. Corrosion 96: The NACE International Annual Conference and Exposition, Houston, USA, NACE-96517.
Ha YC, Bae JH, Gopi D, Ha TH, Lee HG, Kim DH (2004). Studies on the corrosion behavior of aluminium-copper bimetallic sleeves in power distribution system. Bull. Electrochemistry, 20(7), 293-299.
Kucera V, Mattsson E (1982). Atmospheric corrosion of bimetallic structures. Atmospheric Corrosion, Ailor WH, Ed., John Wiley & Sons, New York, 561-574.
LaQue FL (1951). Corrosion testing. Proceedings of American Society for Testing and Materials, Philadelphia, USA, 495-499.
Mansfeld F (1971). Area relationships in galvanic corrosion. Corrosion, 27(10), 136-139.
Mansfeld F, Hengestenberg DH, Kenkel JV(1974). Galvanic corrosion of aluminium alloys–I. Effect of dissimilar metal. Corrosion, 30, 343-353.
Mansfeld F, Kenkel JV (1975a). Area relationship in galvanic corrosion. Corrosion, 31(8), 298-302.
Mansfeld F, Kenkel JV (1975b). Laboratory studies of galvanic corrosion–II. Three-metal couples. Werkstoffe and Korrosion, 26 (9), 699-703.
Mansfeld F, Kenkel JV (1975c). Galvanic corrosion of Al alloys–III. Effect of area ratio. Corrosion Science, 15, 239-250.
Mansfeld F, Kenkel JV (1976). Electrochemical monitoring of atmospheric corrosion phenomena. Corrosion Science, 16(3), 111-114.
Mihit M, Salghi R, El Issami S, Bazzi L, Hammouti B, Aut Addi E, Kertit S (2006). A study of tetrazoles derivatives as corrosion inhibitors of copper in nitric acid. Pigment and Resin Technology, 35(3), 151-157.
Musa AY, Mohamad AB, Kadhum AAH, Eng PC (2011a). Galvanic corrosion of aluminum alloy (Al2024) and copper in 1.0 M nitric acid. International Journal of Electrochemical Science, 6(10), 5052.
Musa AY, Mohamad AB, Kadhum AAH, Tabal YBA (2011b). Inhibition of aluminium alloy corrosion in 0.5 M nitric acid solution by 4-4-dimethyloxazolidine-2-thione. Journal of Materials Engineering and Performance, 20(3), 394-398.
Musa Y, Kadhum AAH, Mohamad AB, Takriff MS (2011c). Inhibition of galvanic corrosion by 4-amino-5-phenyl-4H-1, 2, 4-trizole-3-thiol. International Journal of Surface Science and Engineering, 5(2-3), 226-231.
Rosenfeld IL (1962). Atmospheric corrosion of metals. Some questions of theory. Proceedings of the 1st International congress on metallic corrosion, London, UK, 243-253.
Shreir LL, Jarman RA, Burstein GT (1977). Corrosion: Metal/environmental reactions. Butterworth-Heinemann, London, UK, 152-160.
Vassie PR, Mckensie M (1985). Electrode potentials for on-site monitoring of atmospheric corrosion of steel. Corrosion Science, 25(1), 1-13.
Walker MS (1979). The galvanic corrosion behavior of dissimilar metal couples used in automotive applications. Materials Performance, 8(4), 9-16.
Wilhelm SM(1988). Galvanic corrosion caused by corrosion products. ASTM STP 978 Galvanic Corrosion, Philadelphia, USA, 23-34.
Zhang XG, Valeriote EM (1995). Galvanic protection of steel by zinc under thin layer electrolytes. ASTM STP 1239, Atmospheric Corrosion, Kirk WW, Lawson HH, Eds., American Society for Testing and Materials, Philadelphia, USA, 230-239.
Zhang XG (1998). Galvanic protection distance of zinc coated steels under various environmental conditions. Corrosion, 56(2), 139-143.

Memo

Memo:
-
Last Update: 2014-06-10